Tetrakis(1-ethyl-3-methylimidazolium) β-hexacosaoxidooctamolybdate
نویسندگان
چکیده
منابع مشابه
Impact of two ionic liquids, 1-ethyl-3-methylimidazolium acetate and 1-ethyl-3-methylimidazolium methylphosphonate, on Saccharomyces cerevisiae: metabolic, physiologic, and morphological investigations
BACKGROUND Ionic liquids (ILs) are considered as suitable candidates for lignocellulosic biomass pretreatment prior enzymatic saccharification and, obviously, for second-generation bioethanol production. However, several reports showed toxic or inhibitory effects of residual ILs on microorganisms, plants, and animal cells which could affect a subsequent enzymatic saccharification and fermentati...
متن کاملTetrakis(1-ethyl-3-methylimidazolium) β-hexacosaoxidooctamolybdate
The title compound, (C(6)H(11)N(2))(4)[Mo(8)O(26)] or (emim)(4)[β-Mo(8)O(26)] (emim is 1-ethyl-3-methyl-imidazolium), was obtained from the ionic liquid [emim]BF(4). The asymmetric unit contains two [emim](+) cations and one-half of the [β-Mo(8)O(26)](4-) tetra-anion, which occupies a special position on an inversion centre. The β-[Mo(8)O(26)](4-) tetra-anion features eight distorted MoO(6) coo...
متن کاملSimulations of the water exchange dynamics of lanthanide ions in 1-ethyl-3-methylimidazolium ethyl sulfate ([EMIm][EtSO4]) and water.
The dynamics of ligand exchange on lanthanide ions is important for catalysis and organic reactions. Recent 17O-NMR experiments have shown that water-exchange rates of lanthanide ions in water/1-ethyl-3-methylimidazolium ethyl sulfate (water/[EMIm][EtSO4]) increase as a function of increasing charge density. The trend of water-exchange rates in this solvent is opposite to that observed in water...
متن کاملEnrichment, isolation and characterization of fungi tolerant to 1-ethyl-3-methylimidazolium acetate.
AIMS This work aimed to characterize microbial tolerance to 1-ethyl-3-methylimidazolium acetate ([C2mim][OAc]), an ionic liquid that has emerged as a novel biomass pretreatment for lignocellulosic biomass. METHODS AND RESULTS Enrichment experiments performed using inocula treated with [C2mim][OAc] under solid and liquid cultivation yielded fungal populations dominated by Aspergilli. Ionic...
متن کاملDielectric Relaxation of the Ionic Liquid 1-Ethyl-3-methylimidazolium Ethyl Sulfate: Microwave and Far-IR Properties.
Dielectric relaxation of the ionic liquid, 1-ethyl-3-methylimidazolium ethyl sulfate (EMI+ETS-), is studied using molecular dynamics (MD) simulations. The collective dynamics of polarization arising from cations and anions are examined. Characteristics of the rovibrational and translational components of polarization dynamics are analyzed to understand their respective roles in the microwave an...
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ژورنال
عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online
سال: 2008
ISSN: 1600-5368
DOI: 10.1107/s1600536808015936